Dichlorido{2-[(E)-phenyl(pyridin-2-yl-κN)methylidene]-N-phenylhydrazinecarboxamide-κ2 N 2,O}copper(II)
نویسندگان
چکیده
The title compound, [CuCl2(C19H16N4O)], contains a Cu(II) atom N,N',O-chelated by a neutral N-phenyl-hy-dra-zine-car-box-amide ligand and additionally coordinated by two Cl atoms, resulting in a distorted square-pyramidal geometry. The ligating atoms in the basal square plane of the complex comprise the azomethine N, the pyridine N, the amide O and one of the Cl atoms, whereas the other Cl atom occupies an apical position. The apical Cl atoms in adjacent layers function as hydrogen-bond acceptors to both NH groups. Intermolecular C-H⋯Cl and C-H⋯O interactions are also observed.
منابع مشابه
{(E)-4-Hydroxy-N′-[phenyl(pyridin-2-yl-κN)methylidene]benzohydrazide-κ2 N′,O}bis(nitrato-κ2 O,O′)copper(II)
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عنوان ژورنال:
دوره 69 شماره
صفحات -
تاریخ انتشار 2013